Temperature dependence permittivity property study of (1-x) BaTiO3-xLa2O3 electro ceramic material
DOI:
https://doi.org/10.20372/star.V13i3.01Keywords:
Structure, Permittivity properties, BaTiO3, La2O3, (1-x)BaTiO3-xLa2O3Abstract
High dielectric permittivity materials could be used in dielectric capacitors because of the demands placed on the integration and shrinking of electronic devices. This study's primary goal was to look into the permitivity and structure of (1-X) BaTiO3–(X) La2O3. By using a mixture of BaCO3, La2O3, and TiO2 purity of 99.0-99.9 precursors, a twofold sintering solid state reaction was used to create the (1-X)BaTiO3–(X)La2O3 with (x=0.18) elctro-ceramic nano powder. The sample's structure and permittivity characteristics were ascertained during the characterization procedure using XRD and an impedance analyzer respectively. The crystal structure was determined by XRD examination to be tetragonal, with lattice constants of a = 4.52Ao and c = 5.43Ao. The permittivity measurements' results indicate that when temperature rises, the sample's real permittivity constant and imaginary permittivity party first rises peak and then finally fall. Crystal defects form at higher temperatures, which lead to an increase in interfacial polarization. This means that it is predictable for the dielectric constant to rise as temperature does.
Downloads
Metrics
References
Deng, C., Li, Y., Wang, H., Qu, Y., Qi, X., Peng, Z., Chen, Z., Shen, H., Sun, K., & Fan, R. (2023). Spark plasma sintered graphene/copper calcium titanate ceramic composites with negative permittivity and enhanced thermal conductivity. Ceramics International, 49(10), 16149–16155. https://doi.org/10.1016/j.ceramint.2023.01.212
Huang, X., Yin, R., Qian, L., Zhao, W., Liu, H., Liu, C., Fan, J., Hou, H., Zhang, J., & Guo, Z. (2019). Processing conditions dependent tunable negative permittivity in reduced graphene oxide-alumina nanocomposites. Ceramics International, 45(14), 17784–17792. https://doi.org/10.1016/j.ceramint.2019.05.349
Langmuir, I. (1916). The constitution and fundamental properties of solids and liquids. Part i. Solids. Journal of the American Chemical Society, 38(11), 2221–2295. https://doi.org/10.1021/ja02268a002
Liu, Y., Cheng, C., Zou, J., Fu, J., Wang, J., Zhou, J., Ma, R., Cui, H., Hu, Z., Wang, T., Du, Y., & Fan, R. (2023). Highly tunable negative permittivity of carbon nanofiber/alumina metacomposites at different external temperatures. Composites Part a Applied Science and Manufacturing, 173, 107660. https://doi.org/10.1016/j.compositesa.2023.107660
Ma, R., Cheng, C., Liu, Y., Wang, J., Zhou, J., Hu, Z., Cui, H., Li, J., & Fan, R. (2024). Temperature dependence of negative permittivity behavior in graphene/alumina ceramic metacomposites. Journal of the European Ceramic Society, 44(5), 3012–3019. https://doi.org/10.1016/j.jeurceramsoc.2023.12.016
Merkneh, C., & Tadesse, M. (2020). Fabrication and characterization of perovskite ferroelectric BaTIO3 ceramics from BACO3 and TIO2. International Journal of Innovations in Engineering Research and Technology, 7(11), 1–7. https://repo.ijiert.org/index.php/ijiert/article/view/52
Panda, P. K. (2009). Review: environmental friendly lead-free piezoelectric materials. Journal of Materials Science, 44(19), 5049–5062. https://doi.org/10.1007/s10853-009-3643-0
Petrović, M. V., Bobić, J., Ramoška, T., Banys, J., & Stojanović, B. (2011). Electrical properties of lanthanum doped barium titanate ceramics. Materials Characterization, 62(10), 1000–1006. https://doi.org/10.1016/j.matchar.2011.07.013
Qu, Y., Du, Y., Fan, G., Xin, J., Liu, Y., Xie, P., You, S., Zhang, Z., Sun, K., & Fan, R. (2019). Low-temperature sintering Graphene/CaCu3Ti4O12 nanocomposites with tunable negative permittivity. Journal of Alloys and Compounds, 771, 699–710. https://doi.org/10.1016/j.jallcom.2018.09.049
Rayssi, C., ElKossi, S., Dhahri, J., & Khirouni, K. (2018). Frequency and temperature-dependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1−xCo4x/3O3 (0 ≤ x ≤ 0.1). RSC Advances, 8(31), 17139–17150. https://doi.org/10.1039/c8ra00794b
Ridha, S. M. A., & Najim, M. M. (2015). Synthesis and study the dielectric properties of LA-Doped and undoped barium titanate nanopowders. Engineering and Technology Journal, 33(2B), 298–306. https://doi.org/10.30684/etj.33.2b.14
Song, X., Shi, G., Fan, G., Liu, Y., & Fan, R. (2023). Tunable Negative Permittivity in Graphene/Poly(Vinylidene Fluoride) Composites with Low Percolation Threshold. Advanced Engineering Materials, 26(2). https://doi.org/10.1002/adem.202300203
Sun, Z., Huang, X., Xia, A., Yan, Z., & Qian, L. (2021). Tunable Bandwidth of Negative Permittivity from Graphene-Silicon Carbide Ceramics. Engineered Science. https://doi.org/10.30919/es8d564
Wang, J., Cheng, C., Liu, Y., Zhou, J., Ma, R., Cui, H., Hu, Z., Zou, J., Wang, T., Zhao, Y., & Fan, R. (2024). Tunable negative permittivity performance of carbon/silicon dioxide ceramic metacomposites under external DC bias voltage. Ceramics International, 50(5), 7538–7546. https://doi.org/10.1016/j.ceramint.2023.12.060
Yin, R., Huang, X., & Qian, L. (2019b). Freeze-drying assisted fabrication of highly homogenized reduced graphene oxide/alumina metacomposites with negative permittivity. Ceramics International, 45(5), 5653–5659. https://doi.org/10.1016/j.ceramint.2018.12.030
Downloads
Published
How to Cite
License
Copyright (c) 2024 Journal of Science, Technology and Arts Research
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
STAR © 2023 Copyright; All rights reserved
Accepted 2024-10-08
Published 2024-09-30