Structural and Ferroelectric characteristics of (1-x) NaNbO3-x(Bi0.5Li0.5)TiO3 lead-free electro-ceramic material

Authors

DOI:

https://doi.org/10.20372/star.V14.i1.02

Keywords:

Ferroelectric property, Structure, NaNbO3, (Bi0.5Li0.5)TiO3, NaNbO3-Bi0.5Li0.5TiO3

Abstract

To investigate its structure and ferroelectric properties, a sodium niobate-bismuth lithium titanate ((1-x)NaNbO3-x(Bi0.5Li0.5)TiO3) ceramic with a composition of x = 0.05 was created using a solid-state mixed oxide reaction method. Na2CO3, Nb2O5, Li2CO3, Bi2O3, and TiO2 were used to make the composite. The ((1-x) NaNbO3-x(Bi0.5Li0.5)TiO3) (x = 0.05) exhibits an orthorhombic crystal structure based on the X-ray diffraction pattern. The X-ray diffraction research was measured using an X-ray diffractometer. The morphological inspection is analysed using a scanning electron microscope (SEM). Ferroelectric measurements were performed using the P-E loop tracer. The coercive field (Ec) and remnant polarisation (Pr) of the ceramic sample were observed to rise with increasing applied voltage. Critical evidence from the combined structure and hysteresis loop analysis suggests that the ((1-x)NaNbO3-x(Bi0.5Li0.5)TiO3) (x = 0.05) ceramic is expected to be a potential new lead-free electronic material contender. Hence, ferroelectric materials have many applications, including capacitors, non-volatile memory, piezoelectric for ultrasound imaging and actuators, electro-optic materials for data storage applications, and thermistors.

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Author Biography

Kebede Legesse, Wollega University

Department of Physics, College of Natural and Computational Sciences, Wollega University,

Nekemte, Ethiopia

References

Chaudhari, V. A., & Bichile, G. K. (2010). Structural and impedance spectroscopic studies on PbZrxTi1− xO3 ceramics. Physica B: Condensed Matter, 405(2), 534-539. https://doi.org/10.1016/j.physb.2009.09.060

De Moura, A., Lima, R., Moreira, M., Volanti, D., Espinosa, J., Orlandi, M., Pizani, P., Varela, J., & Longo, E. (2010). ZnO architectures synthesized by a microwave-assisted hydrothermal method and their photoluminescence properties. Solid State Ionics, 181(15–16), 775–780. https://doi.org/10.1016/j.ssi.2010.03.013

Kruczek, M., Talik, E., & Kania, A. (2006). Electronic structure of AgNbO3 and NaNbO3 studied by X-ray photoelectron spectroscopy. Solid State Communications, 137(9), 469–473. https://doi.org/10.1016/j.ssc.2006.01.001

Lente, M., Guerra, J. L. S., Eiras, J., & Lanfredi, S. (2004). Investigation of microwave dielectric relaxation process in the antiferroelectric phase of NaNbO3 ceramics. Solid State Communications, 131(5), 279–282. https://doi.org/10.1016/j.ssc.2004.05.035

Milanez, J., De Figueiredo, A. T., De Lazaro, S., Longo, V. M., Erlo, R., Mastelaro, V. R., Franco, R. W. A., Longo, E., & Varela, J. A. (2009). The role of oxygen vacancy in the photoluminescence property at room temperature of the CaTiO3. Journal of Applied Physics, 106(4). https://doi.org/10.1063/1.3190524

Mishra, S. K., Choudhury, N., Chaplot, S. L., Krishna, P. S. R., & Mittal, R. (2007). Competing antiferroelectric and ferroelectric interactions inNaNbO3: Neutron diffraction and theoretical studies. Physical Review B, 76(2). https://doi.org/10.1103/physrevb.76.024110

Molak, A., Pawełczyk, M., Kubacki, J., & Szot, K. (2009). Nano-scale chemical and structural segregation induced in surface layer of NaNbO3 crystals with thermal treatment at oxidising conditions studied by XPS, AFM, XRD, and electric properties tests. Phase Transitions, 82(9), 662-682. https://doi.org/10.1080/01411590903341155

Moreira, M. L., Mambrini, G. P., Volanti, D. P., Leite, E. R., Orlandi, M. O., Pizani, P. S., & Varela, J. A. (2008). Hydrothermal microwave: a new route to obtain photoluminescent crystalline BaTiO3 nanoparticles. Chemistry of Materials, 20(16), 5381-5387. https://doi.org/10.1021/cm801638d

Morita, T. (2010). Piezoelectric materials synthesized by the hydrothermal method and their applications. Materials, 3(12), 5236-5245. https://doi.org/10.3390/ma3125236

Qiu, S., Fan, H., & Zheng, X. (2006). Pb(Zr0.95Ti0.05)O3 powders synthesized by Pechini method: Effect of molecular weight of polyester on the phase and morphology. Journal of Sol-Gel Science and Technology, 42(1), 21–26. https://doi.org/10.1007/s10971-006-1509-3

Satapathy, S., & Wadhawan, V. K. (2005). Fabrication of pyroelectric laser-energy meters and their characterization using Nd: YAG laser of variable pulse-width. Sensors and Actuators A: Physical, 121(2), 576-583. https://doi.org/10.1016/j.sna.2005.04.004

Selbach, S. M., Tybell, T., Einarsrud, M. A., & Grande, T. (2007). Size-dependent properties of multiferroic BiFeO3 nanoparticles. Chemistry of materials, 19(26), 6478-6484. https://doi.org/10.1021/cm071827w

Shiratori, Y., Magrez, A., Fischer, W., Pithan, C., & Waser, R. (2007). Temperature-induced phase transitions in micro-, submicro-, and nanocrystalline NANBO3. The Journal of Physical Chemistry C, 111(50), 18493–18502. https://doi.org/10.1021/jp0738053

Śmiga, W., & Garbarz-Glos, B. (2008). Structural and mechanical properties of ceramic solid solutions Na1-xLixNbO3 for x≤ 0.06. Ferroelectrics, 377(1), 137-145. https://doi.org/10.1080/00150190802523768

Śmiga, W., Garbarz-Glos, B., Antonova, M., Kalvane, A., & Kuś, C. (2009). The Structural and Dielectric Properties of the Li0. 005Na0. 995NbO3 Ceramics. Ferroelectrics, 379(1), 86-93. https://doi.org/10.1080/00150190902850897

Teixeira, G., Gasparotto, G., Paris, E., Zaghete, M., Longo, E., & Varela, J. (2011). Photoluminescence properties of PZT 52/48 synthesized by microwave hydrothermal method using PVA with template. Journal of Luminescence, 132(1), 46–50. https://doi.org/10.1016/j.jlumin.2011.06.041

Volanti, D. P., Orlandi, M. O., Andrés, J., & Longo, E. (2010). Efficient microwave-assisted hydrothermal synthesis of CuO sea urchin-like architectures via a mesoscale self-assembly. CrystEngComm, 12(6), 1696-1699. https://doi.org/10.1039/D4CE00973H

Xu, G., Jiang, W., Qian, M., Chen, X., Li, Z., & Han, G. (2009). Hydrothermal synthesis of lead zirconate titanate nearly free-standing nanoparticles in the size regime of about 4 nm. Crystal Growth and Design, 9(1), 13-16. https://doi.org/10.1021/cg800287e

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Published

30.03.2025

How to Cite

Legesse, K. (2025). Structural and Ferroelectric characteristics of (1-x) NaNbO3-x(Bi0.5Li0.5)TiO3 lead-free electro-ceramic material. Journal of Science, Technology and Arts Research, 14(1), 11–18. https://doi.org/10.20372/star.V14.i1.02

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Original Research

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Received 2024-11-06
Accepted 2025-03-30
Published 2025-03-30

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