Molecular interaction studies of butyl formate with n-alcohols in carbon tetrachloride at 303K
DOI:
https://doi.org/10.20372/star.v12i3.02Keywords:
Butyl Formate, Alcohols, Ultrasonic velocity, Molecular InteractionAbstract
In ternary mixes of butyl formate with 1-Butanol, 1-Pentanol, and 1-Hexanol, ultrasonic velocities (U), viscosities (ρ), and carbon tetrachloride densities (ρ) have been recorded at 303K. A number of acoustic parameters, including adiabatic compressibility (β), free length (Lf), free volume (Vf), and internal pressure (πi), have been computed using the experimental data. In addition, the molecular interactions, including hydrogen bonds, that occur in combinations of solutes and solvents were utilized to ascertain and clarify the parameter values that were found to be excessive. From what we can see, the effects of homo and hetero association on molecules in alcohols increase as the carbon atom chain lengthens.
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